| Glucose - straight-chain form |
Fructose - straight-chain form |
| Ribose - furanose form |
|
Structure
Pure carbohydrates contain carbon, hydrogen, and oxygen atoms; in a 1:2:1 molar ratio, giving the general formula CxH2xOx. However, many important carbohydrates deviate from this, such as deoxyribose. Sometimes compounds containing other elements are also counted as carbohydrates, such as chitin, which contains nitrogen.
The simplest carbohydrates are monosaccharides, which are small straight-chain aldehydes and ketones with many hydroxyl groups added, usually one on each carbon except the functional group. Other carbohydrates are composed of monosaccharide units, and break down under hydrolysis. These may be classified as disaccharides, oligosaccharides, or polysaccharides, depending on whether they have two, several, or many monosaccharide units.
Monosaccharides may be divided into aldoses, which have an aldehyde group on the first carbon atom, and ketoses, which typically have a ketone group on the second. They may also be divided into trioses, tetroses, pentoses, hexoses, and so forth, depending on how many carbon atoms they contain. For instance, glucose is an aldohexose, fructose a ketohexose, and ribose an aldopentose.
Further, each carbon atom that supports a hydroxyl group (except for the first and last) is optically active, allowing a number of different carbohydrates with the same basic structure. For instance, galactose is an aldohexose, but has different properties from glucose because the atoms are arranged differently.
The straight-chain structure described here is only one of the forms a monosaccharide may take. The aldehyde or ketone group may react with a hydroxyl group on a different carbon atom to form a hemiacetal or hemiketal, in which case there is an oxygen bridge between the two carbon atoms, forming a heterocyclic ring. Rings with five and six atoms are called furanose and pyranose forms, and exist in equilibrium with the straight-chain form.
It should be noted that the ring form has one more optically active carbon than the straight-chain form, and so has both an alpha and a beta form, which interconvert in equilibrium. However, the carbohydrate may further react with an alcohol to form an acetal or ketal, in which case the two forms become distinct. This is the basic type of link between the monosaccharide units of larger carbohydrates.
The most common disaccharides are sucrose (cane or beet sugar - made from one glucose and one fructose), lactose (milk sugar - made from one glucose and one galactose) and maltose (made of two glucoses).
Strictly speaking, carbohydrates are not necessary for human nutrition because proteins can be converted to carbohydrates - the traditional diet of some peoples consists of nearly zero percent carbohydrate, and they are perfectly healthy. However, they require (relatively) less water to digest than proteins or fats, and are an important source of energy.
See also
Monosaccharides
Disaccharides
The formula of these disaccharides is C12H22O11. The binding between the two sugars results in the loss of a hydrogen atom H from one molecule and a hydroxyl group from the other.Nutrition