It is sometimes said that the words orange, purple, and silver are the only words which rhyme with no other words. However, the words sporange, curple, and chilver have been cited as rhymes for these words. That is not to say that there are no rhymeless words, however; there are in fact many, including such words as marathon and discombobulate. If one restricts the list to words of just one or two syllables, however, the list is fairly short. What follows is an attempt at such a list.
List of one- and two-syllable English words without rhymes
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