Kopeikin was born in Kashin, a small town in what was then the USSR. In 1986, he obtained a Ph.D from the Space Research Institute of the Academy of Science of the USSR in Moscow. In 1991, he obtained a Doctor of Science degree from Moscow State University.
He has been married to Zoia Kopeikina (Pikelner) since 1980, and they have four daughters. Since February 2000, they have been living in Columbia, Missouri.
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