While RS-232 originally specified a 25-pin D-type connector, these were large and awkward, and most of the pins were unused (after all, since data is sent one bit at a time, only one wire is needed for data in each direction plus a few control signals), so it was common to use other connectors for these ports (in particular the 9-pin version used by the original IBM PC). In Europe, the related RS-422 standard was popular, and often used German DIN connectors.
In very recent years, more advanced electronics has made possible more reliable and higher-speed serial communications, so RS-232 is being supplanted by newer standards such as USB and Firewire. These make it possible to connect devices that would not have been feasible over slower serial connections, such as storage devices and sound and video devices.